Research

Division of Environmental Technology

1、Research field

Radioactive wastewater treatment technology: a series of technologies and equipment that can achieve near zero radioactive (except for tritium) discharge of liquid effluent from nuclear facilities and minimize radioactive solid waste.Research on membrane materials and membrane technology: hydrophobic membranes, nanofiltration membranes, ion exchange membrane materials, and related technologies and equipment.Research on adsorbent materials: adsorbent materials with high selectivity for nuclidesRadioactive gas purification technology: nuclear air purification and process gas treatment technology, nuclear grade high-efficiency air filters and performance detection technology and devices.Radioactive solid waste treatment technology: cement solidification technology, wet oxidation technology.Application of nuclear technology in environmental protection: Ionization irradiation technology for treating toxic organic pollutants and industrial wastewater.Other technologies: industrial wastewater desalination technology, environmental biotechnology, indoor air purification technology, and biological treatment of heavy metal and radioactive contaminated environments.

2、Projects

The research team has undertaken multiple national projects, including the National Spent Fuel Reprocessing Research Project, National Energy Administration Project, Nuclear Waste Project from National Defense Science and Industry Bureau, National Key Research& and Development Program, National Natural Science Foundation Project, etc.
(1) Research on Low Level Wastewater Treatment Technology (Standardized Design Research)

(2) Research on Low Level Wastewater Treatment Technology

(3) Research on Emergency Treatment Technology and Process for Radioactive Wastewater from Nuclear Accidents

(4) Research on the Mechanism and Methods of Purification of Low Level Radioactive Wastewater under High Salinity Conditions

(5) Development of Hydrophobic Membranes for Treating High Salinity Radioactive Wastewater during the Decommissioning Process

(6) Research on Wet Catalytic Oxidation Technology for Treating Organic Solvent Steam Residue

(7) Research on Environmental Remediation Technology for Low Level Radioactive Polluted Areas

(8) Research on Tracking, Monitoring and Emergency Response Technologies and Equipment for Marine Radioactive Events

(9) Vehicle Mounted Mobile Medical Sewage Irradiation Treatment Integrated Device

(10) Research on Electron Beam Irradiation Technology for Treating Coal Chemical Wastewater

(11) Advanced Treatment for Typical Antibiotic Pharmaceutical Wastewater by Electron-Beam Radiation.

(12) Regulation of the Catalyst with Iron and Cobalt Dual Active Sites for Persulfate Activation towards the Degradation of Antibiotics in the Water.

3、Research Facilities

There are laboratories for radioactive wastewater treatment, water treatment, membrane materials, adsorption materials, radioactive solid waste treatment, cobalt source, and radioactive gas purification, with a total construction area of 1450 m2.
There are various advanced detection instruments, such as inductively coupled plasma mass spectrometry (ICP-MS), high-pressure liquid chromatography (HPLC), ion chromatography, atomic absorption spectroscopy, fluorescence excitation emission matrix EEM instrument, gas chromatography, gamma spectrometer and other advanced analytical instruments. There are several devices for waste treatment, such as mobile treatment device for radioactive wastewater, membrane performance testing platform, membrane system testing platform, adsorbent material testing platform, semi industrial scale membrane material preparation device, adsorbent material preparation platform, performance testing device for high efficiency filter using sodium flame method, radioactive waste cementation equipment.The 60-Cobalt Laboratory was built in 1988 with designed installed capacity of 50000 curies. It is used for the radiation chemistry research with particular on the wastewater treatment. It is the only one Atomic Energy Authority (CAEA) Center of Excellence on Nuclear Technology Application for Electron Beam on Environmental Application in China.

Stationary treatment device for radioactive wastewater

Production line for the adsorbent material

Purification and cooling device for exhaust gas from nuclear power plants

Electron accelerator and radiation reactor for wastewater treatment

4、Academic achievements

Awards

2023 First Prize of Beijing Technological Invention Award, “Key technologies, equipment, and applications of electron beam irradiation for wastewater treatment”

2019 First Prize of Beijing Science and Technology Progress Award, “Novel Technology and Equipment for Radioactive Wastewater Treatment”

2018 First Prize of Science and Technology Award of China Nuclear Energy Industry Association, “Novel Technology and Equipment for Radioactive Wastewater Treatment”

2018 China Patent Excellence Award2018 Second Prize of Beijing Science and Technology

2016 China Patent Excellence Award2014 Second Prize of Beijing Science and Technology Progress

Publications

PublicationsAround 30 publications each year.

Research achievement

(1) Radioactive wastewater treatment technologies and equipment

INET’s research on radioactive wastewater treatment covers the entire stretch from fundamental research to industrial applications, including key technologies, materials and equipment. A series of technical packages have been formed. Engineering demonstrations completed at several nuclear facilities have shown the excellent results, i.e. radioactive decontamination efficiency improved by one to several orders of magnitude. These demonstrations have also shown the advantages in reducing secondary waste production and also in saving the costs of investment and operation. These achievements were awarded the First Prize of the Beijing Science and Technology Progress Awards in 2019, and the First Prize of the China Nuclear Energy Association’s Science and Technology Progress Awards in 2018. The series of integrated systems for treating radioactive wastewater adopts a modular design and is configured based on the characteristics of the wastewater source. It can achieve near zero discharge of nuclides (excluding tritium) from nuclear power plants and minimize radioactive solid waste. It can serve in many situations, such as nuclear power plants, decommissioning of nuclear facilities, and national nuclear emergency.Some main achievements: 

1) a comprehensive and systematic technical system for radioactive wastewater treatment using membrane technology has been constructed, and an innovative refining treatment using electro-driven membrane has been proposed, which can achieve near zero discharge of nuclides (except for tritium) for the radioactive wastewater from nuclear facilities. Developed precision processing core equipment and passed product identification in the nuclear industry; For the first time, a demonstration for radioactive wastewater treatment using membrane technology has been established in a nuclear power plant in China, providing a new means for deep purification of radioactive waste. 

2) A series of adsorption materials for highly selectively adsorbing radioactive nuclides (Sr, Co, Cs, Ag) have been developed, which can efficiently remove target nuclide ions from high salty radioactive wastewater. An industrial production line for adsorption materials has been established, and the prepared adsorption materials have been applied to multiple nuclear facilities, providing support for nuclear power plant operation, nuclear accident emergency response, and nuclear facility decommissioning. 

3) Several membrane materials have been developed, such as reverse osmosis membranes with high retention for nuclide/boron, reverse osmosis membranes for nuclide/boron separation, adsorptive membranes for colloidal nuclides removal, hydrophobic membranes for membrane distillation, nanofiltration membranes for monovalent/multivalent salt separation, and ion exchange membranes for organic matter/salt separation. These membrane materials can not only be used for the radioactive wastewater treatment, but also for industrial wastewater treatment.


(2) Nuclear Air Purification and Process Gas Treatment

INET’s research on nuclear air purification and filter performance testing covers fundamental theory, key technologies, equipment and devices, and engineering applications. Detection methods and the related devices developed at INET have been adopted by the National Standard, i.e. the sodium flame method, the quasimono dispersed counting method, the first nuclear-class high-efficiency air filter in China, the first nuclear-class demister and its performance detection device in China, radioactive gas waste purification devices for spent fuel transportation, activated carbon for radioactive inert gas retention and so on. Related achievements have been applied to nuclear power plants and have received several awards from industrial to provincial and ministerial.Based on the technical basis above mentioned, INET has developed the first high efficiency testing system for mask sealing in China in 2007. The products have been installed at the National Inspection Centers such as Beijing Medical Device Inspection Center and Guangdong Medical Devices Quality Surveillance and Test Institute, serving the needs from public health protection such as SARS and COVID-19.

说明: F:\WORK\601\601相关杂物\课题组简介\空气净化简介照片(20200817)\NLJ-5滤料效率检测台2.jpg

Efficiency testing device for nuclear class high-efficiency filtering materials

说明: F:\WORK\601\601相关杂物\课题组简介\空气净化简介照片(20200817)\口罩密合性检测装置.jpg

Sealing testing system for masks

说明: 高效过滤器效率检测装置2

Performance testing device for high efficiency filter


(3) Ionizing irradiation technology for environmental pollution control

We’ve looked into the radiation degradation characteristics and mechanisms of typical pollutants in a variety of industrial wastewaters, such as polycyclic aromatic hydrocarbons, antibiotics and other refractory toxic organic pollutants using ionizing irradiation technology, and have developed and commercialized advanced treatment technologies for textile dyeing wastewater and harmless treatment technologies for antibiotic fermentation residue by ionizing irradiation.In October 2012, China's first pilot test using a self-shielded electron accelerator to treat cyanide-containing wastewater was carried out in Lianyungang, Jiangsu Province. In October 2016, China's first demonstration project on advanced treatment of industrial wastewater from textile dyeing by electron beam irradiation (2,000 m3/d) was established in Jinghua, Zhejiang Province. In May 2018, Tsinghua University took the lead in formulating the Specification of an Electron Beam for Textile Dyeing and Papermill Wastewater Treatment (T/CNS 8-2018). In June 2020, a plant for textile dyeing wastewater treatment by electron beam, the largest treatment project of its kind in the world, was built in Jiangmen City, Guangdong Province, with a daily treatment capacity of 30,000 tons, which makes China one of the leading countries in the world in terms of electron beam irradiation technology for industrial wastewater treatment, marking the technology’s use for large scale commercialization. In March 2023, the first advanced treatment of coking wastewater by electron beam radiation was established in Tangshan, Hebei Province in China.

Treatment unit of electron beam radiation for dyeing wastewater and the special report about this project in the official website of IAEAThe technology provides a new option for the advanced treatment of refractory industrial wastewater in China. More studies are required to investigate the application potential of electron beam radiation in the field of environmental protection.

(4)Radioactive waste cementationResearch has been conducted on the solidification of spend resin and organic liquid waste, and a special high-efficiency cement solidification formula has been developed and applied to nuclear power plants and nuclear facilities. With the support of National Natural Science Foundation of China, the solidification mechanism and theoretically were explored to guide the optimization of the solidification formula. The nuclear safety standard “Management of Radioactive Waste from the Use of Radioactive Material in Medicine, Industry, Agriculture, Research and Education”, which was drafted by the research group, has been approved to released.

5、Team Member(Nuclear Waste Treatment)

Member

Contact


Xuan Zhao

zhxinet@tsinghua.edu.cn

Team leader & Division Head

Can Chen

chencan@tsinghua.edu.cn


Xiaotong Chen

xiaotongchen@tsinghua.edu.cn


Libing Chu

chulibing@tsinghua.edu.cn


Xuzhou Cheng

chengxz@tsinghua.edu.cn


Shijun He

heshj@tsinghua.edu.cn


Feng Jiang

jf601@tsinghua.edu.cn


Junfeng Li

lijunfeng@tsinghua.edu.cn


Fuzhi Li

li-fz@tsinghua.edu.cn


Jianlong Wang

wangjl@tsinghua.edu.cn


Shizong Wang

wsz2016@tsinghua.edu.cn


Yulong Wu

wylong@tsinghua.edu.cn


Jinling Wu

jinlingwu@tsinghua.edu.cn


Jiying Wei

weijiying@tsinghua.edu.cn


Guoce Yu

yugc@tsinghua.edu.cn


Meng Zhang

zhangmeng@tsinghua.edu.cn


Xue Zhang

zhangxue@tsinghua.edu.cn


Zhenzhong Zhang

zhangzz@tsinghua.edu.cn




(Last Updated: 2024-05-13)