Education background
Ph.D., Peking University, College of Chemistry and Chemical Engineering, 2013
B.S., Peking University, College of Chemistry and Chemical Engineering, 2008
Experience
08/2018-present, Associated Professor, Division of Nuclear Chemistry & Technology, INET
08/2019-07/2020, Visiting Professor, Lawrence Berkeley National Laboratory, USA
07/2013-07/2018, Assistant Professor, Division of Nuclear Chemistry & Technology, INET
Areas of Research Interests/ Research Projects
Dr. Sun’s research interests include chemistry and chemical engineering in the nuclear fuel cycle and coordination chemistry of lanthanides and actinides.
Chemistry and chemical engineering in the nuclear fuel cycle
(1) Process development and optimization for the extraction separation of radionuclides from high-level liquid waste.
(2) Aggregation behavior in the extraction separation of radionuclides using surface-active extractants, primarily associated with the formation of microemulsions.
Coordination chemistry of lanthanides and actinides
(1) Development of new conceptual frameworks for chemical bonding of f-electron by the study on the molecular geometry and electronic structure of lanthanide and actinide complexes using molecular spectroscopy techniques (such as X-ray absorption and emission spectroscopy) in combination with density functional theory (DFT) calculations.
(2) Unraveling the relationship between the extraction ability of extractants and the bond covalency in the complexes of lanthanides and actinides by crystallization, ligand K-edge X-ray absorption spectroscopy (XAS), and density functional theory (DFT) calculations.
Research Status
2020-2023, National Natural Science Foundation of China
Covalency in the complexes of dithiophosphinic acids with lanthanides and actinides
2019-2022, National Natural Science Foundation of China
Coordination chemistry of lanthanides and extraction of the trace ions in ionic liquids
2018-2021, State Administration of Science, Technology and Industry for National Defense
Sub-project IV of the technological research on the separation of high-level liquid waste (Process research, Phase I)
2016-2018, China Association for Science and Technology
Young Elite Scientists Sponsorship (YESS) Program
2015-2018 Tsinghua University
Chemical behavior of key actinides and fission elements in the concentration and denitration of high-level liquid waste
2015-2017, National Natural Science Foundation of China
Study on the microemulsions in the extraction of Ln(III) and An(III) by bis (2,4,4-trimethylpentyl) dithiophosphinic acid
Academic Achievement
Publications
Taoxiang Sun*, Chao Xu, Xiaofeng Xie, Jing Chen, Xuegang Liu*. Quantum chemistry study on the extraction of trivalent lanthanide series by Cyanex301: Insights from formation of inner- and outer-sphere complexes. ACS Omega, 2018, 3: 4070-4080.
Rong Yi, Chao Xu, Taoxiang Sun*, Yaxing Wang, Gang Ye, Shuao Wang, Jing Chen*. Improvement of the extraction ability of bis(2-propyloxy)calix[4]arene-crown-6 toward cesium cation by introducing an intramolecular triple cooperative effect. Separation and Purification Technology, 2018, 199: 97-104.
Wenbing Li, Wuhua Duan, Taoxiang Sun*, Changjian Liu, Jianchen Wang, Jing Chen. Denitration of simulated high-level liquid waste by formic acid for the connection of PUREX process with TRPO process. Journal of Radioanalytical and Nuclear Chemistry, 2017, 314: 199-209.
Taoxiang Sun*, Chao Xu, Jing Chen, Wuhua Duan*. Formation of W/O microemulsions in the extraction of the lanthanide series by purified Cyanex 301. Solvent Extraction and Ion Exchange, 2017, 35: 199-209.
Taoxiang Sun*, Chao Xu, Jing Fu, Qingde Chen, Xinghai Shen*. Extraction of U(VI) by the ionic liquid hexyltributylphosphonium bis (trifluoromethylsulfonyl)imides: An experimental and theoretical study. Separation and Purification Technology, 2017, 188: 386-393.
Taoxiang Sun*, Wuhua Duan, Yaxing Wang, Shaowen Hu, Shuao Wang, Jing Chen, Xinghai Shen*. DFT calculation and experimental validation on the interactions of bis(trifluoromethylsulfonyl)imide and hexafluorophosphate with cesium. Journal of Molecular Structure, 2017, 1148: 206-212.
Taoxiang Sun*, Chao Xu, Jing Chen. Formation of W/O microemulsions in the extraction of Nd(III) by bis(2,4,4-trimethylpentyl)dithiophosphinic acid and its effect on Nd(III) coordination. Dalton Transactions, 2016, 45: 1078-1084.
Taoxiang Sun*, Wuhua Duan, Jinghui Wang, Jianchen Wang, Jing Chen. Hydraulic and mass-transfer performance of a 20-mm-diameter annular centrifugal contactor for the solvent extraction of cesium by bis(2-propyloxy)calix[4]-crown-6 in n-octanol. Solvent Extraction and Ion Exchange, 2015, 33: 75-90.
Last Updated:2020-10-07